JOURNAL OF CHILEAN CHEMICAL SOCIETY

Vol 61 No 3 (2016): Journal of the Chilean Chemical Society
Original Research Papers

CRYSTAL STRUCTURE OF (1,4-DIHYDROXYNAPHTHALEN-2-YL) (4’-METHOXYPHENYL) METHANONE

Julio Benites
Facultad de Ciencia de la Salud, Universidad Arturo Prat
Jaime A. Valderrama
Facultad de Ciencia de la Salud, Universidad Arturo Prat
David Ríos
Facultad de Ciencia de la Salud, Universidad Arturo Prat
Alejandro Cárdenas
Departamento de Física, Facultad de Ciencias Básicas, Universidad de Antofagasta
Iván Brit
Departamento de Química, Facultad de Ciencias Básicas, Universidad de Antofagasta
Published September 10, 2016
Keywords
  • Solar light,
  • Quinones,
  • Diaryl methanones,
  • X-ray diffraction
How to Cite
Benites, J., Valderrama, J. A., Ríos, D., Cárdenas, A., & Brit, I. (2016). CRYSTAL STRUCTURE OF (1,4-DIHYDROXYNAPHTHALEN-2-YL) (4’-METHOXYPHENYL) METHANONE. Journal of the Chilean Chemical Society, 61(3). Retrieved from https://jcchems.com/index.php/JCCHEMS/article/view/98

Abstract

Solar photoacylation of 1,4-naphthoquinone with 4-methoxybenzaldehyde to give (1,4-dihydroxynaphthalen-2-yl)(4’-methoxyphenyl) methanone is one representative example of a general procedure to prepare highly functionalized 1,4-dihydroxynaphthalen-2-yl)(phenyl) methanone derivatives. The structure of the title compound was confirmed by x-ray diffraction analysis of a suitable single crystal. 

References

  1. Olah, G. A. in Friedel-Crafts and Related Reactions, vols. I-IV, Wiley/ Interscience, New YorK, 1963-1964;. Olah, G. A. in: Friedel–Crafts and Related Reactions, Wiley/Interscience, New York, 1973.
  2. Albini, A.; Fagnoni. M.: Green chemistry and photochemistry were born at the same time. Green Chem., 6, (2004), 1-6.
  3. Tundo, P.; Anastas, P.; StC. Black, D.; Breen, J.; Collins, T.; Memoli, S.; Miyamoto, J.; Poliakoff, M.; Tumas, W.: Synthetic pathways and processes in green chemistry. Introductory overview. Pure Appl. Chem., 72, (2000), 1207-1228.
  4. Benites, J.; Cortes, M.; Miranda, L.; Estela, C.; Ríos, D.; Arenas, J.; Valderrama, J. A.: Green Synthetic approaches to furoylnaphthohydroquinone and juglone. J. Ch. Chem. Soc. 59 (2014) 2455-2457.
  5. Arenas, P.; Peña, A.; Ríos D.; Benites, J. Muccioli, G. G.; Buc Calderón, P.; Valderrama, J. A.: Eco-Friendly Synthesis and Antiproliferative Evaluation of Some Oxygen Subtituted Diaryl Ketones. Molecules 18 (2013) 9818-9832.
  6. Sheldrick, G. M.: A short history of SHELX. Acta Cryst. A64, (2008), 112-122.
  7. Dolomanov, O.V.; Bourhis, L.J.; Gildea, R.J.; Howard, J.A.K.; Pus¬chmann, H.: OLEX2: a complete structure solution, refinement and analy¬sis program. J. Appl. Cryst. 42, (2009), 339-341.

Copyright @2019 | Designed by: Open Journal Systems Chile Logo Open Journal Systems Chile Support OJS, training, DOI, Indexing, Hosting OJS

Code under GNU license: OJS PKP