JOURNAL OF CHILEAN CHEMICAL SOCIETY

Vol 63 No 4 (2018): Journal of the Chilean Chemical Society
Original Research Papers

SYNTHESIS, CHARACTERIZATION AND FILM PREPARATION OF NEW CO-POLYIMIDE BASED ON NEW 3,5-DIAMINO-N-(PYRIDIN-4-YLMETHYL)BENZAMIDE, ODA AND 6FDA

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  • Alain Tundidor-Camba,
  • Cesar Saldias,
  • Luis H. Tagle,
  • Claudio A. Terraza,
  • Deysma Coll,
  • Germán Pérez,
  • Manuel Aguilar-Vega,
  • Romina L. Abarca,
  • Pablo A. Ortiz
Alain Tundidor-Camba
Research Laboratory for Organic Polymers, Faculty of Chemistry, Pontificia Universidad Católica de Chile
Cesar Saldias
Physical-Chemistry Department, Faculty of Chemistry, Pontificia Universidad Católica de Chile
Luis H. Tagle
Research Laboratory for Organic Polymers, Faculty of Chemistry, Pontificia Universidad Católica de Chile
Claudio A. Terraza
Research Laboratory for Organic Polymers, Faculty of Chemistry, Pontificia Universidad Católica de Chile
Deysma Coll
Research Laboratory for Organic Polymers, Faculty of Chemistry, Pontificia Universidad Católica de Chile Núcleo de Química y Bioquímica, Facultad de Estudios Interdisciplinarios, Universidad Mayor
Germán Pérez
Research Laboratory for Organic Polymers, Faculty of Chemistry, Pontificia Universidad Católica de Chile
Manuel Aguilar-Vega
Unidad de Materiales. Laboratorio de Membranas. Centro de Investigación Científica de Yucatán A.C.
Romina L. Abarca
Instituto de Ciencia y Tecnología de los Alimentos, Facultad de Ciencias Agrarias, Universidad Austral
Pablo A. Ortiz
Research Laboratory for Organic Polymers, Faculty of Chemistry, Pontificia Universidad Católica de Chile Núcleo de Química y Bioquímica, Facultad de Estudios Interdisciplinarios, Universidad Mayor
Published January 9, 2019
Keywords
  • aromatic co-polyimides,
  • pendant amide,
  • pyridinyl pendant group
How to Cite
Tundidor-Camba, A., Saldias, C., Tagle, L. H., Terraza, C. A., Coll, D., Pérez, G., Aguilar-Vega, M., Abarca, R. L., & Ortiz, P. A. (2019). SYNTHESIS, CHARACTERIZATION AND FILM PREPARATION OF NEW CO-POLYIMIDE BASED ON NEW 3,5-DIAMINO-N-(PYRIDIN-4-YLMETHYL)BENZAMIDE, ODA AND 6FDA. Journal of the Chilean Chemical Society, 63(4). Retrieved from https://jcchems.com/index.php/JCCHEMS/article/view/922

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Abstract

This work describes mainly the synthesis and characterization of new co-polyimides obtained from the polycondensation of the dianhydride 4,4’-(hexafluoroisopropylidene)diphthalic anhydride (6FDA), 4,4’-oxydianiline (ODA) and the new diamine 3,5-diamino-N-(pyridin-4-ylmethyl)benzamide (PyDA). It describes as the different compositions of ODA and PyDA present in the polymers, produce variation on thermal and mechanical properties, which are important characteristics for the development of future nanocomposites derived from these polymers. Both PyDA monomer and polymers were characterized using FT-IR and NMR (1H, 13C, 19F, dept 135°, COSY, HMBC, HMQC) spectroscopy. The inherent viscosity of polymers is between 0.3 to 1.49 dL/g, they are soluble in aprotic polar solvents, such as: DMSO, DMF and DMA. In addition, all co-polymers showed thermal decomposition temperature and glass transition temperatures above 483 °C and 289 °C, respectively. Mechanical tests under tension of co-polymer films showed Young’s modulus between 2.1-3.9 GPa and tensile strength between 35.5 and 120.0 MPa. On the other hand, an increase in crystallinity and hydrophilicity is observed when increasing the amount of pyridinyl groups.

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