JOURNAL OF CHILEAN CHEMICAL SOCIETY

Vol 61 No 3 (2016): Journal of the Chilean Chemical Society
Original Research Papers

THE INHIBITION OF STEEL CORROSION IN ACIDIC SOLUTIONS BY A NEW SCHIFF BASE

N. K. Bakirhan
Department of Analytical Chemistry, Faculty of Pharmacy, Ankara University Hitit University, Science&Literature Faculty, Department of Chemistry
A. Asan
Hitit University, Engineering Faculty, Department of Chemical Engineering
N. Colak
Hitit University, Science&Literature Faculty, Department of Chemistry
S. Sanli
Usak University, Science&Arts Faculty, Department of Chemistry
Published September 10, 2016
Keywords
  • Corrosion inhibitors,
  • Stainless steel,
  • Potentiodynamic polarization,
  • Electrochemical impedance spectroscopy
How to Cite
Bakirhan, N. K., Asan, A., Colak, N., & Sanli, S. (2016). THE INHIBITION OF STEEL CORROSION IN ACIDIC SOLUTIONS BY A NEW SCHIFF BASE. Journal of the Chilean Chemical Society, 61(3). Retrieved from https://jcchems.com/index.php/JCCHEMS/article/view/80

Abstract

The inhibition effect of 2,2’- (((thiobis (4,1 phenylene)) bis(azanylylidene)) bis(methanylyidene)) bis(4-methoxyphenol) (BIS-IMIN) on the corrosion behavior of 304-stainless steel (SS) in 0.5 M HCl solution was studied by electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization techniques. SEM, FT-IR, 1H-NMR, 13C-NMR methods used for characterization of BIS-IMIN. Potentiodynamic polarization curves indicated that BIS-IMIN act as mixed type inhibitor. The adsorption of the inhibitor was more suited with the Langmuir adsorption isotherm and kinetic parameters Kads, ΔGads, Ea , ΔHads, ΔSads were determined at room temperature. The results showed that BIS-IMIN performed well inhibiting effect for the corrosion of the SS. 

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