JOURNAL OF CHILEAN CHEMICAL SOCIETY

Vol 61 No 3 (2016): Journal of the Chilean Chemical Society
Original Research Papers

THE INHIBITION OF STEEL CORROSION IN ACIDIC SOLUTIONS BY A NEW SCHIFF BASE

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  • N. K. Bakirhan,
  • A. Asan,
  • N. Colak,
  • S. Sanli
N. K. Bakirhan
Department of Analytical Chemistry, Faculty of Pharmacy, Ankara University Hitit University, Science&Literature Faculty, Department of Chemistry
A. Asan
Hitit University, Engineering Faculty, Department of Chemical Engineering
N. Colak
Hitit University, Science&Literature Faculty, Department of Chemistry
S. Sanli
Usak University, Science&Arts Faculty, Department of Chemistry
Published September 10, 2016
Keywords
  • Corrosion inhibitors,
  • Stainless steel,
  • Potentiodynamic polarization,
  • Electrochemical impedance spectroscopy
How to Cite
Bakirhan, N. K., Asan, A., Colak, N., & Sanli, S. (2016). THE INHIBITION OF STEEL CORROSION IN ACIDIC SOLUTIONS BY A NEW SCHIFF BASE. Journal of the Chilean Chemical Society, 61(3). Retrieved from https://jcchems.com/index.php/JCCHEMS/article/view/80

Copyright (c) 2017 N. K. Bakirhan, A. Asan, N. Colak, S. Sanli

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Abstract

The inhibition effect of 2,2’- (((thiobis (4,1 phenylene)) bis(azanylylidene)) bis(methanylyidene)) bis(4-methoxyphenol) (BIS-IMIN) on the corrosion behavior of 304-stainless steel (SS) in 0.5 M HCl solution was studied by electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization techniques. SEM, FT-IR, 1H-NMR, 13C-NMR methods used for characterization of BIS-IMIN. Potentiodynamic polarization curves indicated that BIS-IMIN act as mixed type inhibitor. The adsorption of the inhibitor was more suited with the Langmuir adsorption isotherm and kinetic parameters Kads, ΔGads, Ea , ΔHads, ΔSads were determined at room temperature. The results showed that BIS-IMIN performed well inhibiting effect for the corrosion of the SS. 

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References

  1. M. A. Migahed, M. Abd-El-Raouf, A. M. Al-Sabagh, Electrochim Acta 50, 4683, (2005).
  2. A. V. Shanbhag, T. V. Venkatesha, R. A. Prabhu, J Appl Electrochem 38, 279, (2008).
  3. Machnikova, K. H. Whitmire, N. Hackerman, Electrochim Acta 53, 6024, (2008).
  4. K. F. Khaled, Electrochim Acta 53, 3484, (2008).
  5. M. Sahin, G. Gece, F. Karci, J Appl Electrochem 38, 809, (2008).
  6. E. Naderi, A. H. Jafari, M. Ehteshamzadeh, M. G. Hosseini, Mater Chem Phys 115, 852, (2009).
  7. F. Bentiss, M. Lagrenee, M. Traisnel, J. C. Hornez, Corros Sci 417, 89, (1999).
  8. M. E. Achouri, S. Kertit, H. M. Gouttaya, B. Nciri, Y. Bensouda, L. Perez, M. R. Infante, K. Elkacemi, Prog Org Coat 43, 267, (2001).
  9. A. Chetouani, A. Aouniti, B. Hammouti, N. Benchat, T. Benhadda, S. Kertit, Corros Sci 45, 1675, (2003).
  10. R. Solmaz, G. Kardas, M. Culha, B. Yazici, M. Erbil, Electrochim Acta 53, 5941, (2008).
  11. T. Tsuru, S. Haruyama, B. Gijutsu, J Jpn Soc Corros Eng 27, 573, (1978).
  12. L. Elkadi, B. Mernari, M. Traisnel, F. Bentiss, M. Lagrenee, Corros Sci 42, 703, (2000).
  13. F. Bentiss, M. Lebrini, M. Lagrenee, Corros Sci 47, 2915, (2005).
  14. W. Li, Q. He, C. Pei, B. Hou, Electrochim Acta 52, 6386, (2007).
  15. A. Yurta, A. Balaban, S.U. Kandemir, G. Bereket, B. Erk, Mater Chem Phys 85, 420, (2004).
  16. J. Fang, J. Li, J Mol Struct (Theochem.) 593, 179, (2002).
  17. S. S. Abd El-Rehim, H. H. Hassan, M. A. Amin, Corros Sci 46, 5, (2004).
  18. A. K. Maayta, N. A. F. Al-Rawashdeh, Corros Sci 46, 1129, (2004).
  19. L. Tang, X. Li, L. Li, G. Mu, G. Liu, Mat Chem Phys 97, 301, (2006).
  20. S. Kertit, B. Hammouti, Appl Surf Sci 93, 59, (1996).
  21. G. Moretti, F. Guidi, G. Grion, Corros Sci 46, 387, (2004).
  22. O. K. Abiola, N. C. Oforka, Mater Chem Phys 83, 315, (2004).
  23. A. Popova, M. Christov, S. Raicheva, E. Sokolova Corros Sci 46, 1333, (2004).
  24. G. Bereket, E. Hur, C. Ogretir, Molecular Struc (Thochem) 578, 79, (2002).
  25. S. Ashry, A. Nemr, S. A. Essawy, S. Ragab, Prog in Org Coat 61, 11, (2008).
  26. E. A.Noor, A. H. Al-Moubaraki, Mater Chem and Phys 110, 145, (2008).
  27. R. Solmaz, G. Kardas, M. Culha, B. Yazici, M. Erbil, Electrochim Acta 53, 5941, (2008).
  28. S. M. A. Hosseini, A. Azimi, Corros Sci 51, 728, (2009).
  29. G. Avci, Colloids and Surfaces A: Physicochem and Eng Aspects 317, 730, (2008).
  30. M. M. Saleh, Mater Chem Phys 98, 83, (2006).

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