JOURNAL OF CHILEAN CHEMICAL SOCIETY

Vol 63 No 2 (2018): Journal of the Chilean Chemical Society
Original Research Papers

MICROWAVE ASSISTED SYNTHESIS, SPECTRAL CORRELATION AND ANTIMICROBIAL EVALUATION OF SOME ARYL IMINES

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  • S. Pazhinivel Sakthinathan,
  • Ramamoorthy Suresh,
  • Dakshnamoorthy Kamalakkannan,
  • Veerandiran Mala,
  • Kaliyan Sathiyamoorthi,
  • Ganesan Vanangamudi,
  • Ganesamoorthy Thirunarayanan
S. Pazhinivel Sakthinathan
PG & Research Department of Chemistry, Government Arts College, C-Mutlur, Chidambaram-608102
Ramamoorthy Suresh
PG & Research Department of Chemistry, Government Arts College, C-Mutlur, Chidambaram-608102
Dakshnamoorthy Kamalakkannan
PG & Research Department of Chemistry, Government Arts College, C-Mutlur, Chidambaram-608102
Veerandiran Mala
PG & Research Department of Chemistry, Government Arts College, C-Mutlur, Chidambaram-608102
Kaliyan Sathiyamoorthi
PG & Research Department of Chemistry, Government Arts College, C-Mutlur, Chidambaram-608102
Ganesan Vanangamudi
PG & Research Department of Chemistry, Government Arts College, C-Mutlur, Chidambaram-608102
Ganesamoorthy Thirunarayanan
Department of Chemistry, Annamalai University, Annamalainagar-608002
Published June 25, 2018
Keywords
  • Solvent-free synthesis,
  • SiO2-H3PO4,
  • Aryl imines,
  • IR and NMR spectra,
  • Spectral correlation study,
  • Antimicrobial activities
    • ...More
    Less
How to Cite
Sakthinathan, S. P., Suresh, R., Kamalakkannan, D., Mala, V., Sathiyamoorthi, K., Vanangamudi, G., & Thirunarayanan, G. (2018). MICROWAVE ASSISTED SYNTHESIS, SPECTRAL CORRELATION AND ANTIMICROBIAL EVALUATION OF SOME ARYL IMINES. Journal of the Chilean Chemical Society, 63(2). Retrieved from https://jcchems.com/index.php/JCCHEMS/article/view/669

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Abstract

A series of aryl imines have been synthesized by SiO2-H3PO4 catalyzed microwave assisted condensation of amine and aldehyde under solvent-free conditions. The yield of the imines has been found to be more than 80%. The purity of all imines has been checked using their physical constants and spectral data as published earlier in literature. The UV λmax(nm), infrared νC=N(cm-1), NMR δ(ppm) of C-H and C=N spectral data have been correlated with Hammett substituent constants and F and R parameters using single and multi-linear regression analysis. From the results of statistical analysis, the effect of substituents on the above spectral data has been studied. The antimicrobial activities of all imines have been studied using Bauer-Kirby method.

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