JOURNAL OF CHILEAN CHEMICAL SOCIETY

Vol 63 No 1 (2018): Journal of the Chilean Chemical Society
Original Research Papers

EFFICIENT MOLYBDENUM CATALYZED CHEMOSELECTIVE, SOLVENT-FREE OXIDATION OF SULFIDES TO SULFONES AT ROOM TEMPERATURE

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  • Ali Dadashi Hadigavabar,
  • Khalil Tabatabaeian,
  • Mohammad Ali Zanjanchi,
  • Manouchehr Mamaghani
Ali Dadashi Hadigavabar
Department of Chemistry, Faculty of Sciences, University of Guilan
Khalil Tabatabaeian
Department of Chemistry, Faculty of Sciences, University of Guilan
Mohammad Ali Zanjanchi
Department of Chemistry, Faculty of Sciences, University of Guilan
Manouchehr Mamaghani
Department of Chemistry, Faculty of Sciences, University of Guilan
Published April 25, 2018
Keywords
  • Molybdenum,
  • immobilization,
  • selective oxidation,
  • solvent free,
  • sulfide,
  • sulfone
    • ...More
    Less
How to Cite
Hadigavabar, A. D., Tabatabaeian, K., Zanjanchi, M. A., & Mamaghani, M. (2018). EFFICIENT MOLYBDENUM CATALYZED CHEMOSELECTIVE, SOLVENT-FREE OXIDATION OF SULFIDES TO SULFONES AT ROOM TEMPERATURE. Journal of the Chilean Chemical Society, 63(1). Retrieved from https://jcchems.com/index.php/JCCHEMS/article/view/581

Copyright (c) 2018 Journal of the Chilean Chemical Society

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Abstract

An efficient and reusable molybdenum-based catalyst has been prepared by tethering dioxomolybdenumacetylacetonate complex, MoO2(acac)2, via post-synthesis modification of zeolite beta. The catalyst has been characterized by Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy-energy dispersive X-ray analysis (SEM-EDX) and inductively coupled plasma (ICP). The catalyst exhibited very high activity for the selective oxidation of sulfides to sulfones at room temperature. The catalyst can be recycled and reused four times without significant loss of activity.

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