JOURNAL OF CHILEAN CHEMICAL SOCIETY

Vol 61 No 1 (2016): Journal of the Chilean Chemical Society
Original Research Papers

SENSITIVE SIMULTANEOUS DETERMINATION OF PARACETAMOL AND DICLOFENAC BASED ON Au NANOPARTICLES – FUNCTIONALIZED GRAPHENE/POLY (L-ARGININE) GLASSY CARBON ELECTRODE

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  • Esmail Afshar,
  • Fahimeh Jalali
Esmail Afshar
Department of Chemistry, Razi University, 67346, Kermanshah
Fahimeh Jalali
Department of Chemistry, Razi University, 67346, Kermanshah
Published December 10, 2015
Keywords
  • Paracetamol,
  • Diclofenac,
  • Arginine,
  • Au,
  • Graphene,
  • Modified electrode,
  • Voltammetry
    • ...More
    Less
How to Cite
Afshar, E., & Jalali, F. (2015). SENSITIVE SIMULTANEOUS DETERMINATION OF PARACETAMOL AND DICLOFENAC BASED ON Au NANOPARTICLES – FUNCTIONALIZED GRAPHENE/POLY (L-ARGININE) GLASSY CARBON ELECTRODE. Journal of the Chilean Chemical Society, 61(1). Retrieved from https://jcchems.com/index.php/JCCHEMS/article/view/56

Copyright (c) 2016 Esmail Afshar, Fahimeh Jalali

Creative Commons License

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Abstract

A voltammetric sensor was proposed for simultaneous determination of paracetamol and diclofenac based on poly (L-arginine)/Au-graphene nanocomposite film deposited on a glassy carbon electrode. Cyclic voltammetry showed that paracetamol and diclofenac provided well - defined oxidation peaks at +0.443 and +0.644 V, respectively. Experimental parameters, such as the concentration of L-arginine and number of potential cycles in electro-polymerization step, accumulation potential and time, and the pH of buffer solution were optimized. Under the optimized conditions, linear relationships between oxidation peak current and concentration in the range 0.5 – 50.0 μM for paracetamol, and 0.5 – 40.0 μM for diclofenac were obtained in linear sweep voltammetry regime. The limits of detection (LOD) for paracetamol and diclofenac were 0.04 and 0.08 μM, respectively. The fabricated electrode exhibited good reproducibility and stability. The proposed method was successfully applied to the assessment of low concentrations of paracetamol and diclofenac in spiked human blood serum samples with satisfactory results. 

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