Vol 65 No 1 (2020): Journal of the Chilean Chemical Society
Original Research Papers
Published
February 5, 2020
Keywords
- Voltammetry,
- Inhibition,
- Oxide,
- Simulation
How to Cite
lovric, M., & Komorsky-Lovrić, Šebojka. (2020). MODELLING REVERSIBLE INHIBITION OF IRREVERSIBLE ELECTRO-OXIDATION. Journal of the Chilean Chemical Society, 65(1), 4661-4663. Retrieved from https://jcchems.com/index.php/JCCHEMS/article/view/528
Copyright (c) 2020 Journal of the Chilean Chemical Society
This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.
Abstract
Totally irreversible electro-oxidation of dissolved reactant that is inhibited by the formation of oxide on the electrode surface is analysed theoretically. In the reverse, cathodic branch of staircase cyclic voltammogram these two parallel reactions exhibit both cathodic minimum and anodic maximum. The potentials of these extremes depend on the kinetics of oxide formation.
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