JOURNAL OF CHILEAN CHEMICAL SOCIETY

Vol 62 No 4 (2017): Journal of the Chilean Chemical Society
Original Research Papers

NANODECORATION OF SINGLE CRYSTALS OF 5,11,17,23-TETRA-TERT-BUTYL-25,27- BIS(CYANOMETHOXY)-26,28-DIHYDROXYCALIX[4]ARENE

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  • S. Moris,
  • N. Silva,
  • C. Saitz,
  • P. Jara,
  • B. Chornik
S. Moris
Vicerrectoría de Investigación y postgrado, Universidad Católica del Maule
N. Silva
Facultad de Ciencias, Departamento de Química, Universidad de Chile Departamento de Química de Materiales, Universidad de Santiago de Chile
C. Saitz
Departamento de Química Orgánica y Fisicoquímica, Facultad de Ciencias Químicas y Farmacéuticas, Universidad de Chile
P. Jara
Facultad de Ciencias, Departamento de Química, Universidad de Chile
B. Chornik
Departamento de Física, Universidad de Chile
Published February 9, 2018
Keywords
  • Single crystals,
  • 1,
  • 3-bis(cyanomeththoxy)calix[4]arene,
  • nanodecorated,
  • Gold Nanoparticles
How to Cite
Moris, S., Silva, N., Saitz, C., Jara, P., & Chornik, B. (2018). NANODECORATION OF SINGLE CRYSTALS OF 5,11,17,23-TETRA-TERT-BUTYL-25,27- BIS(CYANOMETHOXY)-26,28-DIHYDROXYCALIX[4]ARENE. Journal of the Chilean Chemical Society, 62(4). Retrieved from https://jcchems.com/index.php/JCCHEMS/article/view/476

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Abstract

Single crystals of 1,3-bis(cyanomethoxy)calix[4]arene (1) were grown from Chloroform/Methanol mixture and these were nanodecorated with colloidal gold nanoparticles (AuNps). The single crystals were then characterized by single-crystal X-ray diffraction (XRD) and Scanning Electronic Microscopy (SEM). The nanodecorated crystals were characterized by UV-Visible Absorption Spectroscopy, Transmission Electronic Microscopy (TEM) and X-ray Photoelectron Spectroscopy (XPS). In this work, it is shown that the stabilization of the nanoparticles occurs through of the interactions of these with the nitrile group, maintaining their shape and size.

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