JOURNAL OF CHILEAN CHEMICAL SOCIETY

Vol 62 No 4 (2017): Journal of the Chilean Chemical Society
Original Research Papers

SYNTHESIS AND CHARACTERIZATION OF BISMERCAPTO (2, 2’:6’, 2’’-terpyridine) Ru(II)-COMPLEXES STABILIZED GOLD NANOPARTICLES AND THEIR ELECTRO CATALYTIC REDUCTION OF NITRITE

PDF
  • K. Margandan,
  • M. Jebastin Sonia Jas
K. Margandan
Department of Chemistry, IFET College of Engineering
M. Jebastin Sonia Jas
Department of Chemistry, IFET College of Engineering
Published February 9, 2018
Keywords
  • Ru(II) terpyridine,
  • Au nanopaprticles,
  • thiolates,
  • electro catalytic reduction of nitrite
How to Cite
Margandan, K., & Jebastin Sonia Jas, M. (2018). SYNTHESIS AND CHARACTERIZATION OF BISMERCAPTO (2, 2’:6’, 2’’-terpyridine) Ru(II)-COMPLEXES STABILIZED GOLD NANOPARTICLES AND THEIR ELECTRO CATALYTIC REDUCTION OF NITRITE. Journal of the Chilean Chemical Society, 62(4). Retrieved from https://jcchems.com/index.php/JCCHEMS/article/view/460

Copyright (c) 2018 Journal of the Chilean Chemical Society

Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.

Abstract

Inorganic-organic hybrid structures based on metal-complexes particularly, octahedral bis-2,2’:6’,2’’- terpyridine metal complexes provide an advantages of increased symmetry and in the case of ruthenium(III)/ruthenium(II) complexation an entrance to a directed complexation Method. The Ru (II) terpyridine methane thiolate protected gold nanoparticle was synthesized through covalent bonding of Ru terpyridine methane thiolates over gold nanoparticles surfaces. The ligand terpyridine methanethiolate was synthesized successfully in good percentage of yield. The structures were confirmed and characterized by different physical, analytical, spectral data like FTIR, UV, SEM and Cyclic voltammetry. All the data are shown the expected results.

 

PDF

References

  1. . Kaes, C.; Katz, A,; Hosseini, M. W.; Chem. Rev. 2000, 100, 3553-3590.
  2. . Burstall, F. H.; J. Chem. Soc., 1938, 1662-1672.
  3. . Huynh, M. H. V.; El-Samanody, E. S.; Demadis, K.; White, P. S.; Meyer, T. J.; Inorg.Chem. 2000, 39, 3075-3085.
  4. . Huynh, M. H. V.; White, P. S.; Meyer, T. J.; Inorg. Chem. 2000, 39, 2825-2830.
  5. . Sanna, G.; Pilo, M. I.; Minghetti, G.; Cinellu, M. A.; Spano, N.; Seeber, R.; Inorg. Chim. Acta 2000, 310, 34-40.
  6. . Priimov, G. L.; Moore, P.; Martiim, P. K.; Butalanyi, P. K.; Alcock, N. W.; J. Chem.Soc., Dalton Trans. 2000, 445.
  7. Siebert, R., Winter, A., Dietzek, B., Schubert, U.S. and Popp, J. (2010) MacromolecularRapid Communications, 31,883-888.
  8. Siebert, R., Winter, A., Schubert, U.S., Dietzek, B. and Popp, J. (2010) The Journal of Physical Chemistry C, 114, 6841-6848.
  9. Siebert, R., Winter, A., Schubert, U.S., Dietzek, B. and Popp, J. (2011). Physical ChemistryChemical Physics, 13, 1606-1617.
  10. Binnemans, K., Lenaerts, P., Driesen, K. and Görller-Walrand, C. (2004) Journal of Materials Chemistry, 14, 191-195.
  11. Larsson, K. and Öhrström, L. (2004) Inorganica Chimica Acta, 357, 657- 664.
  12. Steed, J.W. and Atwood, J.L. (2000) Supramolecular Chemistry. Wiley, Chichester.
  13. Chow, C.S. and Bogdan F.M. (1997). Chemical Reviews, 97, 1489-1514.
  14. Sammes, P.G. and Yahioglu, G. (1994) Chemical Society Reviews, 23, 327-334.
  15. Balzani, V., Juris, A., Venturi, M., Campagna, S. and Serroni, S. (1996) Chemical Reviews, 96, 759-834.
  16. Daniel, S. and Gnana Raj, G.A. (2013) Journal of Chemical and Pharmaceutical Research, 5, 220-227.
  17. Smith, N.A. and Sadler, P.J. (2013) Philosophical Transactions of the Royal Society A, 373, 20120519.
  18. Monat, J.E., Rodriguez, J.H. and McCusker, J.K. (2002) Journal of Physical Chemistry A, 106, 7399-7406.
  19. M. RiazianiI, J. Chil. Chem. Soc., 61, Nº 2 (2016) 2870-2877.
  20. Constable, E. C.; Khan, F. K.; Raithby, P. R.; Marquez, V. E.; Acta Crystallogr., Sect. C 1992, 48, 932-934.
  21. Fallahpour, R. A.; Neuburger, M.; Zehnder, M.; New J. Chem. 1999, 23, 53-61.
  22. Bejan, E.; Haddou, H. A.; Darlan, J. C.; Balavoine, G. G. A.; Synthesis 1996, 1012-1018.
  23. Schmid, G.; Baumle, M.; Geerkens, M.; Heim,I.; Osemann, C.; Sawitowski, T. Chem. Soc. Rev. 1999, 28, 179-185.
  24. Liu, J.; Mendoza, S.; Roma´n, E.; Lynn, M. J.; Xu, R.; Kaifer, A.E. J. Am. Chem. Soc. 1999, 121, 4304.
  25. Lehn, J. M.; Supramolecular Chemistry Concepts and PerspectiVes; VCH: Weinheim, 1995; p 144-160.
  26. Constable, E. C.; Cargill Thompson, A. M.; W. J. Chem Soc. Dalton. Trans. 1994, 1409- 1418.
  27. Ca´rdenas, D. J.; Collin, J. P.; Gavin a, P.; Sauvage, J. P.; De Cian, A.; Fischer, J.; Armaroli, N.; Flamigni, L.; Vicinelli,V.; Balzani, V. J. Am. Chem. Soc. 1999, 121, 5481.
  28. Christopher B.; Smith, Colin L.; Raston and Alexandre N.; Sobolev Green Chem., 2005, 7, 650–654.
  29. Constable, E. C.; Handel, R.; Housecroft, C. E.; Neuberger, M.; Schofield E. R., and. Zehnder, M.; Polyhedron, 2004, 23, 135.
  30. Potts, K. T.; Cipullo, M. J.; Ralli P.; and Theodoridis, G.; J. Org.Chem., 1982, 47, 3027.
  31. Bo Tang, Fabiao Yu, Ping Li, Lili Tong, Xia Duan, Ting Xie, and Xu Wang J. Am. Chem. Soc. 9 Vol. 131, NO. 8, 2009.
  32. Guangchang Zhou and Issifu I. Harruna Macromolecules 2005, 38, 4114- 4123.
  33. Shishan Zhang, Gyu Leem, and T. Randall Lee Langmuir 2009, 25, 13855–13860.3699.

Copyright @2019 | Designed by: Open Journal Systems Chile Logo Open Journal Systems Chile Support OJS, training, DOI, Indexing, Hosting OJS

Code under GNU license: OJS PKP