JOURNAL OF CHILEAN CHEMICAL SOCIETY

Vol 61 No 1 (2016): Journal of the Chilean Chemical Society
Original Research Papers

FAST AND RELIABLE METHOD FOR MONITORING EPOXIDATION REACTION IN RECYCLED VEGETABLE OILS (ERVO) USING FTIR-ATR TECHNIQUE

Christian Núñez
Universidad del Bío-Bío, Facultad de Ciencias, Departamento de Química, Av. Collao 1202 Concepción Centro de Biomateriales y Nanotecnología (CBN), Av. Collao, 1202 Concepción
Emilio Vergara
Universidad del Bío-Bío, Facultad de Ciencias, Departamento de Química, Av. Collao 1202 Concepción Centro de Investigación de Polímeros Avanzados, CIPA, Beltrán Mathieu 224, piso 2, Concepción
Justo Lisperguer
Universidad del Bío-Bío, Facultad de Ciencias, Departamento de Química, Av. Collao 1202 Concepción Centro de Investigación de Polímeros Avanzados, CIPA, Beltrán Mathieu 224, piso 2, Concepción
Cynthia Droguett
Universidad del Bío-Bío, Facultad de Ciencias, Departamento de Química, Av. Collao 1202 Concepción Laboratorio de Materiales Compuestos (LMC), Av. Collao, 1202 Concepción
Published December 10, 2015
Keywords
  • Ftir-atr technique,
  • Monitoring epoxidation
How to Cite
Núñez, C., Vergara, E., Lisperguer, J., & Droguett, C. (2015). FAST AND RELIABLE METHOD FOR MONITORING EPOXIDATION REACTION IN RECYCLED VEGETABLE OILS (ERVO) USING FTIR-ATR TECHNIQUE. Journal of the Chilean Chemical Society, 61(1). Retrieved from https://jcchems.com/index.php/JCCHEMS/article/view/39

Abstract

Recycled oils had been a viable alternative for the generation of biodiesel and higher value-added derivatives. Among these derivatives are also bioplasticizers for polymers. Vegetable oils provide a sustainable alternative for plasticizers manufacture, due to the presence of their unsaturation a chemical modification by an epoxidation reaction is possible. Moreover, the use of recycled oils for bioplastificizers preparation is cheaper and profitable. However since it is a complex mixture of vegetable oils, prior characterization of the fatty acids variety making up the mixture to generate bioplasticizer is necessary. Costs associated with monitoring of these kinds of reactions are usually high.

References

  1. -V. Goud, A. Patwardhan, S. Dinda, S. Pradhan. Eur. J. Lipid Sci. Tech. 109:575–584, (2007).
  2. -C. Nuñez, E. Vergara, W. Gacitúa, P. Valenzuela. XXX Jornadas Chilenas de Química. Libro Resumen. Pag. QM312. (2013).
  3. -S. Anuar, Y. Zhao, S. Mugo, J. Curtis. J. Am. Oil Chem. Soc. November 2012, 89(11): 1951-1960, (2012).
  4. -J. Ochoa (coord.). Industria quimica basada en biomasa implicaciones tecnológicas. Informe. Final 2007. Fundación LEIA CDT por encargo de Observatorio Químico del MICYT (2007). 105 pag.
  5. -I. Homer, F. Ruiz, M. Sanchez, P. Calandra. VII Congreso Iberoamericano de Agroingeniería y Ciencias Hortícolas. Madrid, 26-29. Agosto 2013. (2013).
  6. -M. Vieira, M. da Silva, A. Maçumoto, L. Santos, M. Beppu. Mat. Res. Vol.17, n.2, pp. 386-391, (2014).
  7. -T. Saurabh, M. Patnaik, S. Bhagt, V. Renge. International Journal of Advanced Engineering Technology. Vol.II/Issue IV/October-December, 491-501, (2011).
  8. -B. M. Abdullah, J. Salimon. J. Appl. Sci. 10(15):1545–1553, (2010).
  9. -M. Milchert, A. Smagowicz, G. Lewandowski. J Chem. Technol. Biotechnol. 85:1099–1107, (2010).
  10. -M-C. Kuo, T-C. Chou. Ind Eng Chem Res 26(2):277–284, (1987).
  11. -M. Rüsch gen. Klaas, S. Warwel. Ind. Crops Prod., 9, 125–132, (1999).
  12. -M. Guillen, N. Cabo. Food Chem. 77: 503-510, (2002).
  13. -D. Goburdhun, S. Jhaumeer-Laulloo, R. Musruck. Int. J. Food Sci. Nutr. 52 (1) 31-42, (2001).
  14. -Y. Zhang, Y. Zhang, X. Chen, Y. Zhang. Reactive & Functional Polymers 47. 93-99, (2001).
  15. -N. Vlachos, Y. Skopelitis, M. Psaroudaki, V. Konstantinidou, A. Chatzilazarou, E. Tegouet. Analytica Chimica Acta, 573–574: 459–465, (2006).
  16. -ICONTEC. NCT 2366. Aceites vegetales epoxidados de soya y linaza. 11 pag, (2000).
  17. -ICONTEC. NTC 3305. Plásticos. Muestreo y evaluación de los plastificantes utilizados en plásticos. 8 pag, (1997).
  18. -L. Boyacá, A. Beltrán. Ingeniería e Investigación 30(1):136-40, (2010).
  19. -J. Espinoza, D. Haagenson, S. Pryor, C. Ulven, D. Wiesenborn. Transactions of the ASABE. 52(4): 1289-1297, (2009).

Copyright @2019 | Designed by: Open Journal Systems Chile Logo Open Journal Systems Chile Support OJS, training, DOI, Indexing, Hosting OJS

Code under GNU license: OJS PKP