JOURNAL OF CHILEAN CHEMICAL SOCIETY

Vol 68 No 4 (2023): JCChemS
Original Research Papers

SYNTHESIS, STRUCTURAL STUDY, AND MAGNETIC SUSCEPTIBILITY OF THE CHALCOGENIDE OLIVINE COMPOUND Mn2SiTe4

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  • Gerzon E Delgado,
  • Pilar Delgado-Niño,
  • Cecilia Chacón,
  • Gustavo Marroquin,
  • Iván Brito
Gerzon E Delgado
Laboratorio de Cristalografía, Departamento de Química, Facultad de Ciencias, Universidad de Los Andes, Mérida 5101, Venezuela
Bio
Published October 6, 2024
Keywords
  • olivines,
  • chalcogenides,
  • chemical synthesis,
  • X-ray powder diffraction,
  • Rietveld refinement,
  • crystal structure,
  • magnetic susceptibility
    • ...More
    Less
How to Cite
Delgado, G. E., Delgado-Niño, P., Chacón, C., Marroquin, G., & Brito, I. (2024). SYNTHESIS, STRUCTURAL STUDY, AND MAGNETIC SUSCEPTIBILITY OF THE CHALCOGENIDE OLIVINE COMPOUND Mn2SiTe4. Journal of the Chilean Chemical Society, 68(4), 5995-6000. Retrieved from https://jcchems.com/index.php/JCCHEMS/article/view/2609

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Abstract

The ternary material Mn2SiTe4 was synthesized by direct fusion using the annealing method. X-ray powder diffraction analysis indicated that this material crystallizes in the olivine-type structure, space group Pnma, Z = 4, with unit cell parameters: a = 13.905(2) Å, b = 8.128(1) Å, c = 6.526(1) Å, V = 737.6(2) Å3. This olivine structure can be described from a hexagonal close-packing of selenium atoms where manganese atoms occupy ½ of the octahedral sites while silicon atoms lay in ⅛ of the tetrahedra. The magnetic susceptibility curve indicate a possible antiferromagnetic behavior for this material. This compound is related to the ternary layered Mn3Si2Te6 recently studied as possible two-dimensional (2D) magnetic material.

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