JOURNAL OF CHILEAN CHEMICAL SOCIETY

Vol 68 No 1 (2023): Journal of the Chilean Chemical Society
Original Research Papers

RATIONAL DESIGN AND CONVENIENT SYNTHESIS OF TWO NOVEL FERROCENE-BASED SULFONYL DIAMINE PRECURSORS

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  • Rodrigo Arancibia,
  • Miguel Gallardo,
  • Pascal Roussel,
  • Natacha Henry
Rodrigo Arancibia
Departamento de Química Analítica e Inorgánica Facultad de Ciencias Químicas Universidad de Concepcion
Miguel Gallardo
Facultad de Ciencias Químicas, Universidad de Concepción, Concepción, Chile.
Pascal Roussel
Unité de Catalyse et Chimie du Solide, Université de Lille, Lille, France
Natacha Henry
Unité de Catalyse et Chimie du Solide, Université de Lille, Lille, France
Published May 3, 2023
Keywords
  • Cyclic voltammetry,
  • ferrocene,
  • organometallic,
  • sulfonamide,
  • X-ray
How to Cite
Arancibia, R., Gallardo, M., Roussel, P., & Henry, N. (2023). RATIONAL DESIGN AND CONVENIENT SYNTHESIS OF TWO NOVEL FERROCENE-BASED SULFONYL DIAMINE PRECURSORS. Journal of the Chilean Chemical Society, 68(1), 5741-5744. Retrieved from https://jcchems.com/index.php/JCCHEMS/article/view/2276

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Abstract

In the search of new organometallic precursors, this contribution describes a convenient synthesis to obtained new ferrocene-based sulfonyl diamine derivatives. The [(η5-C5H4SO2NH-CH2-CH2-NH2)Fe(η5-C5H5)] (1) and [(η5-C5H4SO2NH-C6H4-NH2)Fe(η5-C5H5)] (2) compounds were prepared by the reaction between (η5-C5H4SO2Cl)Fe(η5-C5H5) and the respective diamine precursor: ethylenediamine (1) or p-phenylenediamine (2) in good yields (86% for 1; 70% for 2). Both compounds were characterized by conventional spectroscopic techniques (infrared spectroscopy, nuclear magnetic resonance spectroscopy, mass spectrometry and elemental analysis) and cyclic voltammetry. In addition, the molecular structure of 1 was determined by single-crystal X-ray diffraction.

2276.JPG

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