JOURNAL OF CHILEAN CHEMICAL SOCIETY

Vol 67 No 3 (2022): Journal of the Chilean Chemical Society
Original Research Papers

EFFECT OF PHOTOSYNTHETIC BACTERIA BASED FEEDSTOCK AND TEMPERATURE ON BIODIESEL YIELD USING MICROWAVE ASSISTED TRANSESTERIFICATION WITH AN APPLICATION OF BOX BEHNKEN SUPPORTED RESPONSE SURFACE METHODOLOGY

Maheswaran Rathinam
Mepco Schlenk Engineering College, Sivakasi
Uthranarayan
Mepco Schlenk Engineering College, Sivakasi
Published September 2, 2022
Keywords
  • transesterification,
  • biodiesel,
  • algae,
  • photosynthetic bacteria
How to Cite
Rathinam, M., & C, U. (2022). EFFECT OF PHOTOSYNTHETIC BACTERIA BASED FEEDSTOCK AND TEMPERATURE ON BIODIESEL YIELD USING MICROWAVE ASSISTED TRANSESTERIFICATION WITH AN APPLICATION OF BOX BEHNKEN SUPPORTED RESPONSE SURFACE METHODOLOGY. Journal of the Chilean Chemical Society, 67(3), 5636-5642. Retrieved from https://jcchems.com/index.php/JCCHEMS/article/view/2151

Abstract

Algae based third generation biodiesel production is a recent advancement in renewable energy due to its minimal land requirements, cultivation in wastelands etc than food stock based second generation biodiesel production. This paper addresses on the study the optimum yield of biodiesel produced from oxygenic photosynthetic bacteria-based Spirulina Platensis algae by microwave assisted transesterification. Effect of microwave irradiation time which affects the temperature on the extraction of algal oil and simultaneous in-situ transesterification was investigated for biodiesel production. The response surface methodology using Box Behnken Design was used to analyze constituent parameters like catalyst concentration, alcohol concentration and process parameters like microwave time. Results indicate that microwave assisted transesterification produces 71.7% of biodiesel with respect to algae dry weight at catalyst concentration of 1.6%, with alcohol concentration of 1:9.7 and microwave irradiation time of 3.2 minutes

 

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References

  1. Killi D, Bussotti F, Gottardini E, et al. Photosynthetic and morphological responses of oak species to temperature and [CO2] increased to levels predicted for 2050. Urban Forestry and Urban Greening. 31, 26–37 (2018).
  2. Capellán-Pérez I, Mediavilla M, de Castro C, Carpintero Ó, Miguel LJ. Fossil fuel depletion and socio-economic scenarios: An integrated approach. Energy. 77, 641–666 (2014).
  3. Peña-Farfal C, Moreda-Piñeiro A, Bermejo-Barrera A, Bermejo-Barrera P, Pinochet-Cancino H, de Gregori-Henríquez I. Speeding up enzymatic hydrolysis procedures for the multi-element determination in edible seaweed. Journal of the Chilean Chemical Society. 548(1–2), 183–191 (2005).
  4. Sheehan JJ. Biofuels and the conundrum of sustainability. Current Opinion in Biotechnology20(3), 318–324 (2009).
  5. Balat M. Potential alternatives to edible oils for biodiesel production – A review of current work. Energy Conversion and Management. 52(2), 1479–1492 (2011).
  6. IEA. Net Zero by 2050. IEA, Paris (2020).
  7. Bošnjaković M, Sinaga N. The perspective of large-scale production of algae biodiesel. Applied Sciences (Switzerland)10(22), 1–26 (2020).
  8. Mondal B, Parhi SS, Rangaiah GP, Jana AK. Nano-catalytic heterogeneous reactive distillation for algal biodiesel production: Multi-objective optimization and heat integration. Energy Conversion and Management. 241 (2021).
  9. B. Brentner L, J. Eckelman M, B. Zimmerman J. Combinatorial Life Cycle Assessment to Inform Process Design of Industrial Production of Algal Biodiesel. Environmental Science & Technology. 45(16), 7060–7067 (2011).
  10. Pokoo-Aikins G, Nadim A, El-Halwagi MM, Mahalec V. Design and analysis of biodiesel production from algae grown through carbon sequestration. Clean Technologies and Environmental Policy. 12(3), 239–254 (2010).
  11. Abdallah S E, Wagih S S, Olfat M S, Mosaad A K. A review on biodiesel feedstocks and production technologies. Journal of the Chilean Chemical Society. 66(1), 5098–5109 (2021).
  12. Jacob A, Ashok B, Alagumalai A, Chyuan OH, Le PTK. Critical review on third generation micro algae biodiesel production and its feasibility as future bioenergy for IC engine applications. Energy Conversion and Management228 (2021).
  13. Partha M. Green Chemistry – A Novel Approach towards Sustainability. Journal of the Chilean Chemical Society. 66(1), 5075–5080 (2021).
  14. Jiménez C, Cossío BR, Niell FX. Relationship between physicochemical variables and productivity in open ponds for the production of Spirulina: a predictive model of algal yield. Aquaculture. 221(1–4), 331–345 (2003).
  15. Radmann EM, Reinehr CO, Costa JAV. Optimization of the repeated batch cultivation of microalga Spirulina platensis in open raceway ponds. Aquaculture. 265(1–4), 118–126 (2007).
  16. Uslu L, Işik O, Koç K, Göksan T. The effects of nitrogen deficiencies on the lipid and protein contents of Spirulina platensis. African Journal of Biotechnology [Internet]. 10(3), 386–389 (2011). Available from: http://www.academicjournals.org/AJB.
  17. Ma F, Hanna MA. Biodiesel production: a review. Bioresource Technology. 70(1), 1–15 (1999).
  18. Suat E, Mahire B, Ahmet G, Fevli O, Hatice K. EMISSION ANALYSIS ON THE INFLUENCE OF FERROFLUID ON RICE BRAN BIODIESEL. Journal of the Chilean Chemical Society. 62(4), 3661–3667 (2017).
  19. Wahlen BD, Willis RM, Seefeldt LC. Biodiesel production by simultaneous extraction and conversion of total lipids from microalgae, cyanobacteria, and wild mixed-cultures. Bioresource Technology. 102(3), 2724–2730 (2011).
  20. Tabatabai B, Chen H, Lu J, et al. Fremyella diplosiphon as a Biodiesel Agent: Identification of Fatty Acid Methyl Esters via Microwave-Assisted Direct In Situ Transesterification. Bioenergy Research. 11(3), 528–537 (2018).
  21. Plessis ; Kaufman KREB, Shulz J, Morgan RP. Variables Affecting the Yields of Fatty Esters from Transesterified Vegetable Oils 1. Weswiew Press.
  22. Meher LC, Vidya D, Naik SN. Technical aspects of biodiesel production by transesterification-a review, Renewable and sustainable energy reviews, 10. 248-268.
  23. Yahya S, Muhamad Wahab SK, Harun FW. Optimization of biodiesel production from waste cooking oil using Fe-Montmorillonite K10 by response surface methodology. Renewable Energy. 157, 164–172 (2020).
  24. Srikanth H v., Venkatesh J, Godiganur S. Box-Behnken Response Surface Methodology for Optimization of Process Parameters for Dairy Washed Milk Scum Biodiesel Production. Biofuels. 12(1), 113–123 (2021).
  25. Chamola R, Khan MF, Raj A, Verma M, Jain S. Response surface methodology based optimization of in situ transesterification of dry algae with methanol, H2SO4 and NaOH. Fuel. 239, 511–520 (2019).
  26. Boldor D, Kanitkar A, Terigar BG, et al. Supporting Information Microwave assisted extraction of biodiesel feedstock from the seeds of invasive Chinese tallow tree. .
  27. Nayak MG, Vyas AP. Optimization of microwave-assisted biodiesel production from Papaya oil using response surface methodology. Renewable Energy. 138, 18–28 (2019).
  28. Ajaz A, Mohammad R, Khalid A, Kazi M, Faiyaz S. BOX-BEHNKEN SUPPORTED DEVELOPMENT AND VALIDATION OF ROBUST RP-HPLC METHOD_ AN APPLICATION IN ESTIMATION OF PRAVASTATIN IN BULK AND PHARMACEUTICAL DOSAGE FORM. Journal of the Chilean Chemical Society. 61(2), 2963–2967 (2016).
  29. Onumaegbu C, Alaswad A, Rodriguez C, Olabi A. Modelling and optimization of wet microalgae Scenedesmus quadricauda lipid extraction using microwave pre-treatment method and response surface methodology. Renewable Energy. 132, 1323–1331 (2019).
  30. Hasnain M, Abideen Z, Naz S, Roessner U, Munir N. Biodiesel production from new algal sources using response surface methodology and microwave application. Biomass Conversion and Biorefinery. (2021).
  31. Pazhanivel S, Ramamuthy S, Dakshnamoorthy K, Veerandiran M. MICROWAVE ASSISTED SYNTHESIS, SPECTRAL CORRELATION AND ANTIMICROBIAL EVALUATION OF SOME ARYL IMINES. Journal of the Chilean Chemical Society. 63(2), 3918–3923 (2018).
  32. Nagle N, Lemke P. Production of Methyl Ester Fuel from Microalgae, Applied biochemistry and biotechnology, 24, 255-361.
  33. Vijayaraghavan K, Hemanathan K. Biodiesel production from freshwater algae. Energy and Fuels. 23(11), 5448–5453 (2009).
  34. Hamdi K, Vladimir Z, Sema A. PREPARATION AND APPLICATION OF KOH IMPREGNATED SEPIOLITE AS A SOLID BASE CATALYST FOR BIODIESEL PRODUCTION USING MICROWAVE IRRADIATION. Journal of the Chilean Chemical Society. 4(66), 5320–5323 (2021).
  35. Hasnain M, Abideen Z, Naz S, Roessner U, Munir N. Biodiesel production from new algal sources using response surface methodology and microwave application. Biomass Conversion and Biorefinery. (2021).
  36. Perreux L, Loupy AÂ. Tetrahedron report number 588 A tentative rationalization of microwave effects in organic synthesis according to the reaction medium, and mechanistic considerations Contents 1. Origin of microwave effects. .
  37. Yang J, Xu M, Zhang X, Hu Q, Sommerfeld M, Chen Y. Life-cycle analysis on biodiesel production from microalgae: Water footprint and nutrients balance. Bioresource Technology. 102(1), 159–165 (2011).
  38. Jessy Pavon P, Carlos Pena F, Mario A, Karem Henriquez A. OPTIMIZATION AND VALIDATION OF A LIQUID CHROMATOGRAPHIC METHOD FOR DETERMINATION OF CAPSAICIN IN CHILI PEPPERS. Journal of the Chilean Chemical Society. 64(2), 4475–4479 (2019).
  39. Mondal SK, Saha AK, Sinha A. Removal of ciprofloxacin using modified advanced oxidation processes: Kinetics, pathways and process optimization. Journal of Cleaner Production. 171, 1203–1214 (2018).
  40. Nazzal S, Khan MA. Response Surface Methodology for the Optimization of Ubiquinone Self-Nanoemulsified Drug Delivery System [Internet]. . Available from: http://www.aapspharmscitech.org.
  41. Jesse Pavon P, Carlos Pena F, Mario Aranda, Karem Henriquez A. OPTIMIZATION AND VALIDATION OF A LIQUID CHROMATOGRAPHIC METHOD FOR DETERMINATION OF CAPSAICIN IN CHILI PEPPERS. Journal of the Chilean Chemical Society. 64(2), 4475–4479 (2019).
  42. Majid M, Massoud K, Mohammad H, Ahmad Jamali K, Sayyed Hossein H. APPLICATION OF RESPONSE SURFACE MODELING FOR OPTIMIZATION AND DETERMINATION OF MALONDIALDIALDEHYDE BY VORTEX-ASSISTED DISPERSIVE LIQUID-LIQUID MICROEXTRACTION AND GC-FID. Journal of the Chilean Chemical Society. 64(3), 4531–4537 (2019).
  43. Patil PD, Gude VG, Mannarswamy A, et al. Optimization of microwave-assisted transesterification of dry algal biomass using response surface methodology. Bioresource Technology. 102(2), 1399–1405 (2011).
  44. Leadbeater NE, Barnard TM, Stencel LM. Batch and continuous-flow preparation of biodiesel derived from butanol and facilitated by microwave heating. Energy and Fuels. 22(3), 2005–2008 (2008).
  45. Patil PD, Gude VG, Camacho LM, Deng S. Microwave-assisted catalytic transesterification of camelina sativa oil. Energy and Fuels. 24(2), 1298–1304 (2010).
  46. Encinar JM, González JF, Rodríguez JJ, Tejedor A. Biodiesel fuels from vegetable oils: Transesterification of Cynara cardunculus L. Oils with ethanol. Energy and Fuels. 16(2), 443–450 (2002).
  47. Leila Kafi A, Shahin K, Mehrin Nasafzadeh N, Abdol Ali A, Majid M, Ahmad Foursattar M. Co-PRECIPITATION SYNTHESIS, CHARACTERIZATION OF CoFe2O4 NANOMATERIAL AND EVALUATION OF ITS TOXICITY BEHAVIOR ON HUMAN LEUKEMIA CANCER K562 CELL LINE. Journal of the Chilean Chemical Society. 65(2), 4845–4848 (2020).
  48. Patil PD, Gude VG, Mannarswamy A, et al. Optimization of direct conversion of wet algae to biodiesel under supercritical methanol conditions. Bioresource Technology. 102(1), 118–122 (2011).

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