Vol 67 No 3 (2022): Journal of the Chilean Chemical Society
Original Research Papers
Published
September 12, 2022
Keywords
- Chalcones,
- Cyclic Voltammetry,
- DFT calculations,
- HOMO-LUMO levels,
- optoelectronic materials
How to Cite
Moreno, Y., Brovelli, F., & Ahumada, G. (2022). SUBSTITUTED HETEROCYCLIC CHALCONES: ELECTROCHEMICAL, SPECTROSCOPIC AND THEORETICAL STUDY. Journal of the Chilean Chemical Society, 67(3), 5662-5666. Retrieved from https://jcchems.com/index.php/JCCHEMS/article/view/2101
Copyright (c) 2022 SChQ
This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.
Abstract
We have studied the electronic and electrochemical properties of seven substituted heterocyclic chalcones (CHL 1-6) wich are functionalized with 2-thienyl groups. The phenyl ring of the chalcone scaffold has been substituted in orto or para position with electron donnor and acceptor groups (-F, -NO2, -CH3O). The electrochemical features were analyzed by cyclic voltammetry; irreversible processes were observed and attributed to the oxidation and reduction of the 2-thienyl group and the carbonyl group of the chalcone, respectively. DFT calculations were made to gain more in-depth understanding of their electronic properties. Relatively high HOMO level and low LUMO values were calculated, Eg values computed varies between 3.0-3.29 eV. These values enable us to postulate that these type of compounds are suitable building blocks to fabricate optoelectronic devices.
References
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[22] Chang-Ji Zheng, Sheng-Ming Jiang, Zhen-Hua Chen, Bai-Jun Ye, and Hu-Ri Piao, Arch. Pharm. Chem. Life Sci. 344(10) (2011) 689-695.
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[25], F. Brovelli, R. Baggio, L. Alvarez, Y. Moreno, Journal of Chilean Chemical Society 66 (2) (2021) 5190-5194.
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[53] K. Tremel, S. Ludwigs Adv. Polym. Sci., 265 (2014) 39-82
[54] P. Acevedo-Peña, A. Baray-Calderón, H. Hu, I. González, V.M. Ugalde-Saldivar, J. Solid State Electrochem., 21 (2017) 2407-2414
[55] P.J. Tejkiran, M.S. Brahma Teja, P Sai Siva Kumar, P. Sankar, R. Philip, S. Naveen, N.K. Lokanath, G. Nageswara Rao J. Photochemistry Photobiology A: Chemistry 324 (2016) 33-39.
[56] S. Sathish, B. Chandar Shekar, S. Chandru Kannan, R. Sengodan, K.P.B. Dinesh, R. Ranjithkumar Int. J. Polym. Anal. Charact. 20(1) (2015) 29-41.
[57] Dian Alwani Zainuri, Ibrahim Abdul Razak and Suhana Arshad, Acta Cryst. E Crystallogr. Comun. 74 (10) (2018) 1491-1496.
[58] Ainizatul Husna Anizaim, Muhamad Fikri Zaini, Muhammad Adlan Laruna, Ibrahim Abdul Razak, S. Arshad Acta Cryst. E Crystallogr. Comun. 75(5) (2019) 632-637.
