JOURNAL OF CHILEAN CHEMICAL SOCIETY

Vol 66 No 4 (2021): Journal of the Chilean Chemical Society
Original Research Papers

PREPARATION AND APPLICATION OF KOH IMPREGNATED SEPIOLITE AS A SOLID BASE CATALYST FOR BIODIESEL PRODUCTION USING MICROWAVE IRRADIATION

Sema Aslan
Mugla Sitkş Kocman University Chemistry Department
Published December 29, 2021
Keywords
  • Heterogenous catalysis, KOH, sepiolite, rapeseed oil, microwave assisted transesterification, biodiesel production
How to Cite
Karaoğlu, M. H., Zholobenko, V., & Aslan, S. (2021). PREPARATION AND APPLICATION OF KOH IMPREGNATED SEPIOLITE AS A SOLID BASE CATALYST FOR BIODIESEL PRODUCTION USING MICROWAVE IRRADIATION. Journal of the Chilean Chemical Society, 66(4), 5320-5323. Retrieved from https://jcchems.com/index.php/JCCHEMS/article/view/1801

Abstract

An active basic solid catalyst for biodiesel production was obtained via KOH impregnation onto sepiolite support followed by high temperature calcination. The transesterification of rapeseed oil over the resulting nanocomposite structure was investigated using a microwave reactor. Morphological and structural characterization of sepiolite and KOH impregnated sepiolite was carried out by Fourier transform infrared spectroscopy, X-ray diffraction, scanning electron microscopy and energy dispersive spectroscopy analysis. Optimization of the operational parameters such as methanol to oil molar ratio, catalyst loading, reaction temperature and reaction time were examined. Reusability of the catalyst and the reactions utilizing waste cooking oil were also studied. Obtained results indicated that the basic heterogeneous catalysis diminishes the saponification during the transesterification reaction and that microwave heating was very effective at shortening the biodiesel production time. However, the reusability of the KOH impregnated sepiolite catalysts and their structural stability require further investigation

1801.JPG

References

  1. References
  2. I.K. Hong, H. Jeon, H. Kim, S.B. Lee, J. Ind. Eng. Chem. 42, 107, (2016)
  3. I. Fatimah, D. Rubiyanto, J. Nugrah, Sus. Chem. Pharm. 8, 63, (2018)
  4. A.T. Hoang, M. Tabatabaei, M. Aghbashlo, Energy Sour. Part A. 42, 2923, (2019)
  5. R.S. Pasupathy, T. Mohanraj, Energy Sour. Part A. 43, 172, (2019)
  6. M. Tomar, N. Kumar, Energy Sour. Part A. 42, 2944, (2019)
  7. F. Ma, M.A. Hanna, Bioresour. Technol. 70, 1, (1999)
  8. A. Al-Ani, R. Gertisser, V. Zholobenko, Appl. Clay Sci. 162, 297, (2018)
  9. A. Al-Ani, R.J. Darton, S. Sneddon, V. Zholobenko, ACS Appl. Nano Mater. 1, 310, (2018)
  10. Y. Wang, X. Wang, Y. Liu, S. Ou, Y. Tan et al. Fuel Proc. Technol.; 90, 422, (2009)
  11. Z. Helwani, M.R. Othman, N. Aziz, J. Kim, W.J.N. Fernando. Appl. Catal. A General. 363, 1, (2009)
  12. M. Zabeti, M. Wan, D. Wan. Fuel Proc. Technol. 90, 770, (2009)
  13. A.K. Sarma, J.K. Sarmah, L. Barbora, P. Kalita, S. Chatterjee et al. Recent Patents on Eng. 2, 47, (2008)
  14. J.S. Lee, S. Saka. Bioresour. Technol. 101, 7191, (2010)
  15. M. Canakci, J. Van Gerpan. Transactions-Am. Soc. Agric. Eng. 44, 1429, (2001)
  16. M.L. Grandos, M.D. Poves, D. Alonso, R. Mariscal, F.C. Galisteo et al. Appl. Catal. B: Env. 73, 317, (2007)
  17. J. Ji, J. Wang, Y. Li, Y. Yu, Z. Xu. Ultrason. 44, 411, (2006)
  18. K.S. Kumar, C. Anju. Bioresour. Technol. 96, 1425, (2005)
  19. T. Ebiura, T. Echizen, A. Ishikawa, M. Kazuhito, T. Baba. Appl.Catal. A: General. 283, 111, (2005)
  20. W. Xie, P. Hong, C. Ligong. J. Mol. Catal. A: Chem. 246, 24, (2006)
  21. D. Fabbri, V. Bevoni, M. Notari, F. Rivetti. Fuel. 86, 690, (2007)
  22. L. Wang, J. Yang. Fuel. 86, 328, (2007)
  23. G. Arzamendi, I. Campoa, E. Arguinarena, M. Sanchez, M. Montes et al. Chem. Eng. J. 134, 123, (2007)
  24. D. E. Lopez, D. A. Bruce Jr, J.G.E. Lotero. Appl. Cat. A: General.295,105, (2005)
  25. T. Tateno, T. Sasaki. Process for producing fatty acid fuels comprising fatty acids esters. Uni. State Patent 6818026, November 16, 2004.
  26. M. Di. Serio, R. Tesser, M. Dimiccoli, F. Cammarota, M. Nasatasiet al. J. Mol. Catal. 239, 111, (2005)
  27. H. Mootabadi, B. Salamatinia, S. Bhatia, A.Z. Abdullah. Fuel. 89, 1818, (2010)
  28. B. Salamatinia, H. Mootabadi, S. Bhatia, A.Z. Abdullah. Fuel Proc. Technol. 91, 441, (2010)
  29. D.J. Vujicic, D. Comic, A. Zarubica, R. Micic, G. Boskovic. Fuel. 89, 2054, (2010)
  30. B. Yoosuk, P. Udomsap, P. Buppa, K. Pawnprapa. Chem. Eng. J. 162, 135, ( 2010)
  31. S.J. Yoo, H.S. Lee, V. Bambang, J. Kim, J.D. Kim et al. Bioresour. Technol. 101, 8686, (2010)
  32. W.M. Antunes, C.O. Veloso, C.A. Henriques. Catal. Today. 133–135, 548, (2008)
  33. O. Ilgen. Fuel Proc. Technol. 92, 452, (2011)
  34. A. Alsalme, E.F. Kozhevnikova, I.V. Kozhevnikov. Appl. Catal. A: General. 349, 170, (2008)
  35. Y.M. Park, D. Lee, D.K. Kim, J. Lee, K.Y. Lee. Catal. Today. 131, 238, (2008)
  36. Y.M. Park, S. Chung, H.J. Eom, J. Lee, K. Lee. Bioresour. Technol. 101, 6589, (2010)
  37. A.C. Alba-Rubio, F. Vila, D.M. Alonso, M. Ojeda, R. Mariscalet al. Appl. Catal. B: Environ. 95, 279, (2010)
  38. A.M. Dehkhoda, A.H. West, N. Ellis. Appl. Catal. A: General. 382, 204, (2010)
  39. C. Guo, F. Baishan. Bioresour. Technol. 102, 2635, (2011)
  40. D.C. Deka, S. Basumatary, J.S. Lee. Biomass and Bioenergy. 305, 1797, (2011)
  41. R. Chakraborty, S. Bepari, A. Banerjee. Bioresour. Technol. 102, 3610, (2011)
  42. M. Agarwal, G. Chauhan, S.P. Chaurasia, K. Singh. J. Taiwan Inst. Chem. Eng. 43, 94, (2012)
  43. L. Wu, T.Y. Wei, Z.F. Tong, Y. Zou, Z.J. Lin et al. Fuel Proc. Technol. 144, 340, (2016)
  44. M. Menor, S. Sayas, A. Chica. Fuel. 193, 358, (2017)
  45. J. Shi, Y. Li, Q. Zhang, X. Ma, L. Duan et al. Appl. Energy 203, 421, (2017)
  46. C.H. Zhou, G.L. Li, X.Y. Zhuang, P.P. Wang, D.S. Tong et al. Mol. Cat. 434, 231, (2017)
  47. I. Reyero, A. Moral, F. Bimbela, J. Radosevic, O. Sanzet al. Fuel. 182, 676, (2016)
  48. S. Aslan, N. Aka, M.H. Karaoğlu. Energy Sour. Part A. 41, 297, (2019)
  49. W.N.N.W. Omar, N.A.S. Amin. Fuel Proc. Technol. 92, 2405, (2011)
  50. M. Cobas, L. Ferreira, M.A. Sanroman, M. Pazos. EcologicalEngineering.40,294,(2014)
  51. E. Eren, O. Cubuk, H. Ciftci, B. Eren, B. Caglar. Desalin.252,96,(2010)
  52. H. Shahraki, M.H. Entezari, E.K. Goharshadi. UltrasonicsSonochemistry.23,274,(2015)
  53. M. Takase, Y. Chen, H. Liu, T. Zhao, L. Yang et al. Ultrasonics Sonochemistry. 21, 1762, (2014)
  54. H. Wu, J. Zhang, Q. Wei, J. Zheng, J. Zhang. Fuel Proc. Technol. 109, 18, (2013)

Copyright @2019 | Designed by: Open Journal Systems Chile Logo Open Journal Systems Chile Support OJS, training, DOI, Indexing, Hosting OJS

Code under GNU license: OJS PKP