RAMAN AND X-RAY FLUORESCENCE TO IDENTIFY COLORS OF THE GERMAN HYPERINFLATION STAMPS OF THE 1923 COLLECTION
- Archaeophilately,
- German hyperinflation postage stamps,
- forgery,
- Raman spectrum,
- XRF
- β-naphthol azopigments,
- Prussian blue,
- crocoite,
- zinc oxide ...More
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Abstract
Colors of a collection set of postage stamps dated 1923 and corresponding to the hyperinflationary period of the German economy were identifiedwith Raman and X-ray fluorescence (XRF) spectroscopies. Molecular systems associated to the blue, green and yellow colours were characterized. Blue colour is Prussian blue (Fe4[Fe(CN)6]3) and the green colour resulted to be a combination of Prussian blue and the yellow/orange pigment (PbCrO4) or a yellow β-naphthol like monoazopigment. The XRF data suggest that ZnO was used as filler.
References
- P. Raento and S.D. Brunn. Visualizing Finland postage stamps as political messengers. Geografiska Annaler: Series B, Human Geography, 87 (2005) 145-164.
- S.D. Brunn. Stamps as iconography: Celebrating the independence of new European and Central Asian states. GeoJournal, 52 (2000) 315-323.
- D. Gentleman. Stamps as signs. RSA Journal, 143 (1995) 68-70.
- B. Davis. Maps on Postage Stamps as Propaganda. The Cartographic Journal, 22 (1985) 125-130.
- T. Lewes and E.L. Pemberton. Forged stamps: how to detect them. Colston and Son: Edimburgh - https://archive.org/, 1863; p 36, 39 p.
- J.-S. Gómez-Jeria, E. Clavijo, J. Cárcamo-Vega and S. Gutierrez. An infrared and SEM study of the margins of some German hyperinflation postage stamps. Research Journal of Pharmaceutical, Biological and Chemical Sciences, 9 (2018) 870-892.
- S.H. Zeronian and H.L. Needles. Historic Textile and Paper Materials II. American Chemical Society: 1989; Vol. 410, p 276.
- M. Derrick. Evaluation of the state of degradation of dead sea scroll samples using FT-IR spectroscopy. Book Paper Group Annual, (1991) 10.
- G. Righini, A.L. Segre, G. Mattogno, C. Federici and P.F. Munafò. An X-ray photoelectron spectroscopic study of ancient paper and its deterioration. Naturwissenschaften, 85 (1998) 171-175.
- M.C. Sistach, N. Ferrer and M.T. Romero. Fourier Transform Infrared Spectroscopy Applied to the Analysis of Ancient Manuscripts. In Restaurator, 19 (1998) 173.
- M.R. Derrick, D. Stulik and J.M. Landry. Infrared spectroscopy in conservation science. Getty Publications: 2000.
- M. Poslusny and K.E. Daugherty. Nondestructive Adhesive Analysis on Stamps by Fourier Transform Infrared Spectroscopy. Applied Spectroscopy, 42 (1988) 1466-1469.
- J.H.A. Wang. Versatile Analytical Method of Identifying Adhesive on Stamps by Specular-Reflectance Fourier Transform Infrared Spectroscopy. Applied Spectroscopy, 44 (1990) 447-450.
- T.D. Chaplin, R.J.H. Clark and D.R. Beech. Comparison of genuine (1851-1852 AD) and forged or reproduction Hawaiian Missionary stamps using Raman microscopy. Journal of Raman Spectroscopy, 33 (2002) 424-428.
- T.D. Chaplin, A. Jurado-López, R.J.H. Clark and D.R. Beech. Identification by Raman microscopy of pigments on early postage stamps: distinction between original 1847 and 1858–1862, forged and reproduction postage stamps of Mauritius. Journal of Raman Spectroscopy, 35 (2004) 600-604.
- R.J. Weiss and D.R. Chartier. Fakebusters II: Scientific Detection of Fakery in Art and Philately. World Scientific: 2004; Vol. 4.
- K. Castro, B. Ábalos, I. Martínez-Arkarazo, N. Etxebarria and J.M. Madariaga. Scientific examination of classic Spanish stamps with color error, a non-invasive micro-Raman and micro-XRF approach: The King Alfonso XIII (1889–1901 “Pelón”) 15 cents. J. Cultural Heritage, 9 (2008) 189-195.
- E. Imperio, G. Giancane and L. Valli. Spectral Database for Postage Stamps by Means of FT-IR Spectroscopy. Analytical Chemistry, 85 (2013) 7085-7093.
- E. Imperio, G. Giancane and L. Valli In Fourier transform infrared spectroscopy (FTIR) investigation focused on Italian postage stamps in the course of time, 3rd Workshop-Plasmi, Sorgenti, Biofisica ed Applicazioni, 2013; 2013; pp 49-52
- H.G. Brittain. Attenuated Total Reflection Fourier Transform Infrared (ATR FT-IR) Spectroscopy as a Forensic Method to Determine the Composition of Inks Used to Print the United States One-cent Blue Benjamin Franklin Postage Stamps of the 19th Century. Applied Spectroscopy, 70 (2016) 128-136.
- J.J. Melendez-Perez, D.N. Correa, V.V. Hernandes, D.R. de Morais, R.B. de Oliveira, W. de Souza, J.M. Santos and M.N Eberlin. Forensic Application of X-ray Fluorescence Spectroscopy for the Discrimination of Authentic and Counterfeit Revenue Stamps. Applied Spectroscopy, 70 (2016) 1910-1915.
- N.V. Schwab, J.A. Da-Col, P. Meyer, M.I.M.S. Bueno and M.N. Eberlin Energy Dispersive X-Ray Fluorescence Profile of Some Brazilian Postage Stamps. Journal of the Brazilian Chemical Society, 27 (2016) 1305-1310.
- J.S. Gómez-Jeria and E. Clavijo A preliminary infrared study of the cellulose of some world stamps. Chemistry Research Journal, 2 (2017) 191-197.
- J.S. Gómez-Jeria, E. Clavijo and Gutiérrez S. An Infrared and SEM study of the margins of some Estonian postage stamps. Research Journal of Pharmaceutical, Biological and Chemical Sciences, 9 (2018) 1258-1279.
- B. Widdig. Culture and inflation in Weimar Germany. University of California Press: Berkeley, 2001; p xvi, 277 p.
- Michel Deutschland-Spezial. Band 1. Schwaneberger: Unterschleißheim, 2016.
- D. Lin-Vien, N.B. Colthup, W.G. Fateley and J.G. Grasselli, The handbook of infrared and Raman characteristic frequencies of organic molecules, Elsevier, 1991.
- N.C. Scherrer, Z. Stefan, D. Francoise, F. Annette and K. Renate, Spectrochim. Acta Part A: Molecular and Biomolecular Spectroscopy, 73 (2009) 505-524.
- R. Downs, The RRUFF Project: an integrated study of the chemistry, crystallography, Raman and infrared spectroscopy of minerals, in: Program and abstracts of the 19th general meeting of the international mineralogical association in Kobe, Japan. O03-13, 2006.
- E. Imperio, G. Giancane and L. Valli, Analyst, 140 (2015) 1702-1710.
- E. Imperio, E. Calò, L. Valli and G. Giancane,. Vib. Spectrosc., 79 (2015) 52-58.
- A. Ismail, M.J. Abdullah, J. King Saud Univ.-Sci., 25 (2013) 209-215.