JOURNAL OF CHILEAN CHEMICAL SOCIETY

Vol 64 No 3 (2019): Journal of the Chilean Chemical Society
Original Research Papers

CRYSTAL STRUCTURE OF (E)-N'-((1H-PYRROL-2-YL)METHYLENE)-4-HYDROXYBENZOHYDRAZIDE

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  • Ghodrat Mahmoudi,
  • Sadegh Rostamnia,
  • Guillermo Zaragoza,
  • Iván Brito,
  • Jonathan Cisterna,
  • Alejandro Cárdenas
Ghodrat Mahmoudi
Department of Chemistry, Faculty of Science, University of Maragheh
Sadegh Rostamnia
Department of Chemistry, Faculty of Science, University of Maragheh
Guillermo Zaragoza
Unidad de RX, Edificio CACTUS, Campus Vida
Iván Brito
Departamento de química Universidad de Antofagasta
Jonathan Cisterna
Departamento de química Universidad de Antofagasta
Alejandro Cárdenas
Departamento física Universidad de Antofagasta
Published October 30, 2019
Keywords
  • Hydrazide,
  • X-ray diffracction,
  • non-covalent interactions,
  • Hirshfeld surface,
  • energy framework
How to Cite
Mahmoudi, G., Rostamnia, S., Zaragoza, G., Brito, I., Cisterna, J., & Cárdenas, A. (2019). CRYSTAL STRUCTURE OF (E)-N’-((1H-PYRROL-2-YL)METHYLENE)-4-HYDROXYBENZOHYDRAZIDE. Journal of the Chilean Chemical Society, 64(3), 4496-4501. Retrieved from https://jcchems.com/index.php/JCCHEMS/article/view/1309
Copyright Notice

Abstract

The title compound corresponds to an enaminone E isomer in the solid state. X-ray structure shows that this crystallizes in the orthorrombic system, with space group Pna21 with 2 independent molecules in the asymmetric unit in a non-centrosymmetric setting. The CNNC unit forms dihedral angles of 5.9(3)/2.1(3); 19.7(3)/17.6(3)° with the pyrrole and phenol rings for molecules A and B respectively. The main differences between both molecules is the dihedral torsion between rings, their mean planes form dihedral angles of 25.45(15) and 15.38(15)° for the molecules A and B. In the asymmetric unit, molecules are linked by two weak N – H···O hydrogen bonds with set graph-motif

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