JOURNAL OF CHILEAN CHEMICAL SOCIETY

Vol 65 No 2 (2020): Journal of the Chilean Chemical Society
Original Research Papers

PREPARATION AND APPLICATION OF GLUTARALDEHYDE CROSS-LINKED CHITOSAN COATED BENTONITE CLAY CAPSULES: CHROMIUM(VI) REMOVAL FROM AQUEOUS SOLUTION

Türkan ALTUN
Bio
Published July 18, 2020
Keywords
  • Composite,
  • Chitosan,
  • Bentonite clay,
  • Cr(VI),
  • Adsorption,
  • Isotherm
  • ...More
    Less

Abstract

New sources in literature have explained that more efficient biosorbents can be developed from natural adsorbents. One of the methods to make these natural adsorbents more efficient is preparation of composites. Hydroxyl (-OH) and amino (-NH2) groups within the structure of chitosan leads adsorbents to have a binding potential with heavy metals. In this study, a composite adsorbent made of chitosan and bentonite clay was prepared. Bentonite clay and chitosan-coated Bentonite clay composite capsules (BC) were characterized in terms of FTIR and SEM analysis. (BC) composite adsorbent was used for the adsorption of Cr(VI) ions from aqueous solution. The effects of some parameters such as pH, adsorbent dosage, adsorbate concentration, temperature and contact time on the adsorption of Cr(VI) on BC were investigated. In order to evaluate the experimental data, Langmuir, Freundlich, Scatchard and Dubinin-Radushkevich (D-R) adsorption isotherm models were used for the analysis of adsorption equilibrium. The adsorption process was well fitted to Scatchard adsorption isotherm. While bentonite clay had 11,076 mg/g maximum adsorption capacity, BC composite had 106.444 mg/g maximum adsorption capacity for the removal of Cr(VI) ions (25 °C, pH 2, contact time 60 minutes). It was concluded that chitosan-bentonite composite adsorbent can be effectively used for the removal of Cr(VI).

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References

  1. Mudzielwana, R., Gitari, M. W., Akinyemi, S. A., & Msagati, T. A. M. Performance of Mn 2+-modified bentonite clay for the removal of fluoride from aqueous solution. South African Journal of Chemistry, 71(1), 15. (2018)
  2. Edebali, S. Alternative Composite Nanosorbents Based on Turkish Perlite for the Removal of Cr(VI) from Aqueous Solution. Journal of Nanomaterials, 2015. (2015)
  3. Auta, M., & Hameed, B. H. Chitosan-clay composite as highly effective and low-cost adsorbent for batch and fixed-bed adsorption of methylene blue. Chemical Engineering Journal, 237, 352. (2014)
  4. Fida, H., Guo, S., & Zhang, G. Preparation and characterization of bifunctional Ti-Fe kaolinite composite for Cr(VI) removal. Journal of Colloid and Interface Science. (2015)
  5. Uddin, M. K. A review on the adsorption of heavy metals by clay minerals, with special focus on the past decade. Chemical Engineering Journal. (2017)
  6. Ghomri, F., Lahsini, A., Laajeb, A., & Addaou, A. The removal of heavy metal ions (copper, zinc, nickel and cobalt) by natural bentonite. LARHYSS Journal ISSN 1112-3680, (12). (2013)
  7. Niazi, L., Lashanizadegan, A., & Sharififard, H. Chestnut oak shells activated carbon: Preparation, characterization and application for Cr (VI) removal from dilute aqueous solutions. Journal of Cleaner Production. (2018)
  8. Gupta, V. K., Chandra, R., Tyagi, I., & Verma, M. Removal of hexavalent chromium ions using CuO nanoparticles for water purification applications. Journal of Colloid and Interface Science. (2016)
  9. Yang, J., Yu, M., & Chen, W. Adsorption of hexavalent chromium from aqueous solution by activated carbon prepared from longan seed: Kinetics, equilibrium and thermodynamics. Journal of Industrial and Engineering Chemistry. (2015)
  10. Ghaneian, M. T., Bhatnagar, A., Ehrampoush, M. H., Amrollahi, M., Jamshidi, B., Dehvari, M., & Taghavi, M. Biosorption of hexavalent chromium from aqueous solution onto pomegranate seeds: kinetic modeling studies. International Journal of Environmental Science and Technology. (2017)
  11. Qi, W., Zhao, Y., Zheng, X., Ji, M., & Zhang, Z. Adsorption behavior and mechanism of Cr(VI) using Sakura waste from aqueous solution. Applied Surface Science. (2016)
  12. Nasseh, N., Taghavi, L., Barikbin, B., & Khodadadi, M. Advantage of almond green hull over its resultant ash for chromium(VI) removal from aqueous solutions. International Journal of Environmental Science and Technology. (2017)
  13. Khalfa, L., Cervera, M. L., Bagane, M., & Souissi-Najar, S. Modeling of equilibrium isotherms and kinetic studies of Cr (VI) adsorption into natural and acid-activated clays. Arabian Journal of Geosciences, 9(1), 75. (2016)
  14. Rathnayake, S. I., Martens, W. N., Xi, Y., Frost, R. L., & Ayoko, G. A. Remediation of Cr (VI) by inorganic-organic clay. Journal of Colloid and Interface Science. (2017)
  15. Qiu, W., Yang, D., Xu, J., Hong, B., Jin, H., Jin, D., Wang, X. Efficient removal of Cr (VI) by magnetically separable CoFe2O4/activated carbon composite. Journal of Alloys and Compounds, 678, 179. (2016)
  16. Vunain, E., Mishra, A. K., & Mamba, B. B. Dendrimers, mesoporous silicas and chitosan-based nanosorbents for the removal of heavy-metal ions: A review. International Journal of Biological Macromolecules. (2016)
  17. Alhaji, N. M. I., & Begum, K. M. T. M. Optimization and Kinetic Study for the Removal of Chromium (VI) Ions by Acid Treated Sawdust Chitosan Composite Beads. International Research Journal of Pure and Applied Chemistry, 5(2), 160. (2015)
  18. Moussout, H., Ahlafi, H., Aazza, M., & El Akili, C. Performances of local chitosan and its nanocomposite 5%Bentonite/Chitosan in the removal of chromium ions (Cr(VI)) from wastewater. International Journal of Biological Macromolecules, 108, 1063. (2018)
  19. Liu, Q., Yang, B., Zhang, L., & Huang, R. Adsorptive removal of Cr(VI) from aqueous solutions by cross-linked chitosan/bentonite composite. Korean Journal of Chemical Engineering, 32(7), 1314. (2015)
  20. Chen, L., Wu, P., Chen, M., Lai, X., Ahmed, Z., Zhu, N., … Liu, T. Preparation and characterization of the eco-friendly chitosan/vermiculite biocomposite with excellent removal capacity for cadmium and lead. Applied Clay Science. (2018)
  21. Biswas, S., Islam, M. M., Hasan, M. M., Rimu, S. H., Khan, M. N., Haque, P., & Rahman, M. M. Evaluation of Cr (VI) Ion Removal from Aqueous Solution by Bio-Inspired Chitosan-Clay Composite: Kinetics and Isotherms. Iranian Journal of Chemical Engineering, 15(4). (2018)
  22. Yadav, V. B., Gadi, R., & Kalra, S. Clay based nanocomposites for removal of heavy metals from water: A review. Journal of environmental management, 232, 803. (2019)
  23. Sargin, I., Kaya, M., Arslan, G., Baran, T., & Ceter, T. Preparation and characterisation of biodegradable pollen-chitosan microcapsules and its application in heavy metal removal. Bioresource Technology, 177, 1. (2015)
  24. Moussout, H., Ahlafi, H., Aazza, M., & Amechrouq, A. Bentonite/chitosan nanocomposite: preparation, characterization and kinetic study of its thermal degradation. Thermochimica Acta, 659, 191. (2018)
  25. Giannakas, A., & Pissanou, M. Chitosan/Bentonite Nanocomposites for Wastewater Treatment: A Review. SF J Nanochem Nanotechnol. 2018; 1 (1), 1010. (2018)
  26. Futalan, C. M., Kan, C. C., Dalida, M. L., Hsien, K. J., Pascua, C., & Wan, M. W. Comparative and competitive adsorption of copper, lead, and nickel using chitosan immobilized on bentonite. Carbohydrate Polymers. (2011)
  27. Waheed Thany, Z., & Mousa Ridha, A. Use of chitosan impregnated modified bentonite as an adsorbent for remediation of oil spill from aqueous solution. International Journal of Engineering & Technology, 7(4), 4380. (2018)
  28. Zou, C., Jiang, W., Liang, J., Sun, X., & Guan, Y. Removal of Pb (II) from aqueous solutions by adsorption on magnetic bentonite. Environmental Science and Pollution Research, 26(2), 1315. (2019)
  29. Ugwu, I. M., & Igbokwe, O. A. Sorption of Heavy Metals on Clay Minerals and Oxides: A Review. In Advanced Sorption Process Applications. IntechOpen. (2019)
  30. Altun, T., Parlayıcı, Ş., & Pehlivan, E. Hexavalent chromium removal using agricultural waste “rye husk”. Desalination and Water Treatment. (2016)
  31. Melo, J. S., & D’Souza, S. F. Removal of chromium by mucilaginous seeds of Ocimum basilicum. Bioresource Technology. (2004)
  32. Matouq, M., Jildeh, N., Qtaishat, M., Hindiyeh, M., & Al Syouf, M. Q. The adsorption kinetics and modeling for heavy metals removal from wastewater by Moringa pods. Journal of Environmental Chemical Engineering. (2015)
  33. Li, J., Cai, J., Zhong, L., Cheng, H., Wang, H., & Ma, Q. Adsorption of reactive red 136 onto chitosan/montmorillonite intercalated composite from aqueous solution. Applied Clay Science, 167, 9. (2019)
  34. Zhao, Y., Qi, W., Chen, G., Ji, M., & Zhang, Z. Behavior of Cr(VI) removal from wastewater by adsorption onto HCl activated Akadama clay. Journal of the Taiwan Institute of Chemical Engineers. (2015)
  35. Akram, M., Bhatti, H. N., Iqbal, M., Noreen, S., & Sadaf, S. Biocomposite efficiency for Cr(VI) adsorption: Kinetic, equilibrium and thermodynamics studies. Journal of Environmental Chemical Engineering. (2017)
  36. Mishra, A., Dubey, A., & Shinghal, S. Biosorption of chromium(VI) from aqueous solutions using waste plant biomass. International Journal of Environmental Science and Technology. (2015)
  37. Georgieva, V. G., Tavlieva, M. P., Genieva, S. D., & Vlaev, L. T. Adsorption kinetics of Cr(VI) ions from aqueous solutions onto black rice husk ash. Journal of Molecular Liquids. (2015)
  38. Pandey, S., & Mishra, S. B. Organic-inorganic hybrid of chitosan/organoclay bionanocomposites for hexavalent chromium uptake. Journal of Colloid and Interface Science, 361(2), 509. (2011)
  39. Fouodjouo, M., Fotouo-Nkaffo, H., Laminsi, S., Cassini, F. A., de Brito-Benetoli, L. O., & Debacher, N. A. Adsorption of copper (II) onto cameroonian clay modified by non-thermal plasma: Characterization, chemical equilibrium and thermodynamic studies. Applied Clay Science. (2017)
  40. Lin, J., Wu, Y., Khayambashi, A., Wang, X., & Wei, Y. Preparation of a novel CeO2/SiO2 adsorbent and its adsorption behavior for fluoride ion. Adsorption Science and Technology, 36(1–2), 743. (2018)
  41. Ayawei, N., Ebelegi, A. N., & Wankasi, D. Modelling and Interpretation of Adsorption Isotherms. Journal of Chemistry. (2017)
  42. Parlayici, S. Alginate-coated perlite beads for the efficient removal of methylene blue, malachite green, and methyl violet from aqueous solutions: kinetic, thermodynamic, and equilibrium studies. Journal of Analytical Science and Technology, 10(1), 4. (2019)
  43. Chaudhry, S. A., Khan, T. A., & Ali, I. Equilibrium, kinetic and thermodynamic studies of Cr(VI) adsorption from aqueous solution onto manganese oxide coated sand grain (MOCSG). Journal of Molecular Liquids. (2017)
  44. Liu, X., & Lee, D. Thermodynamic parameters for adsorption equilibrium of heavy metals and dyes from wastewaters. Bioresource Technology, 160, 24. (2014)
  45. Salih, S. S., & Ghosh, T. K. Highly efficient competitive removal of Pb (II) and Ni (II) by chitosan/diatomaceous earth composite. Journal of environmental chemical engineering, 6(1), 435. (2018)
  46. Tulun, S., Bahadir, T., Simsek, I., & Karatas, M. THE REMOVAL OF NICKEL IONS WITH WALNUT SHELL. Turkish Journal of Engineering (TUJE), 3(2), 102. (2019)
  47. Konicki, W., & Pełech, I. Removing Cationic Dye from Aqueous Solutions Using as-grown and Modified Multi-Walled Carbon Nanotubes. Polish Journal of Environmental Studies,

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