JOURNAL OF CHILEAN CHEMICAL SOCIETY

Vol 64 No 2 (2019): Journal of the Chilean Chemical Society
Original Research Papers

CRYSTAL STRUCTURE AND HIRSHFELD SURFACE ANALYSIS OF (E)-5-PHENYL-3-((4- (TRIFLUOROMETHYL)BENZYLIDENE)AMINO)THIAZOLIDIN-2-IMINIUM BROMIDE

Abel M. Maharramov
Organic Chemistry Department, Baku State University
Gulnara Sh. Duruskari
Organic Chemistry Department, Baku State University
Gunay Z. Mammadova
Organic Chemistry Department, Baku State University
Ali N. Khalilov
Organic Chemistry Department, Baku State University Department of Physics and Chemistry, "Composite Materials" Scientific Research Center, Azerbaijan State Economic University (UNEC)
Javahir M. Aslanova
Organic Chemistry Department, Baku State University
Jonathan Cisterna
Departamento de Química, Facultad de Ciencias Básicas, Universidad de Antofagasta
Alejandro Cárdenas
Departamento de Física, Facultad de Ciencias Básicas, Universidad de Antofagasta
Iván Brito
Departamento de Química, Facultad de Ciencias Básicas, Universidad de Antofagasta
Published July 25, 2019

Abstract

In the cation of the title salt, the central thiazolidine ring adopts an envelope conformation. In the crystal N-H ··· Br hydrogen bonds link the components into a bi-dimensional network with the cations and anions stacked parallel to plane (101). The molecular structure shows several positional disorders over -CF3 and thiazolidine fragments and these were modeled. The weak intermolecular interactions in the crystal structure are mainly constituted by H ··· F, H ··· π and H ··· Br. Hirshfeld surface analysis were used to verify the contributions of the different intermolecular interactions.

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