JOURNAL OF CHILEAN CHEMICAL SOCIETY

Vol 64 No 2 (2019): Journal of the Chilean Chemical Society
Original Research Papers

REMOVAL OF CR(VI) BY STABILIZED SOLVENT IMPREGNATED RESIN (SIR) PREPARED BY USING A HYDROPHILIC POLYMER ADSORBENT AND ALIQUAT 336

Daniela V. Morales
University of Concepción, Faculty of Chemistry, Polymer Department Ege University, Department of Chemical Engineering
Ozge Kusku
Ege University, Department of Chemical Engineering Ege University, Department of Chemistry
Bernabé L. Rivas
University of Concepción, Faculty of Chemistry, Polymer Department
Muserref Arda
Ege University, Department of Chemistry
Nalan Kabay
Ege University, Department of Chemical Engineering
Marek Bryjak
Wroclaw University of Science and Technology, Department of Polymer and Carbon Materials
Published July 25, 2019
Keywords
  • Ion exchange resins,
  • solvent impregnated resin (SIR),
  • Chromium,
  • Adsorption

Abstract

The solvent impregnated resin (SIR) was prepared by using Diaion HP-2MG as a hydrophilic polymer adsorbent and commercial Aliquat 336 as extractant for hexavalent chromium Cr(VI) removal from aqueous solution. The resulting SIRs were stabilized by coating using poly(vinyl alcohol) (PVA) and divinylsulfone as crosslinking reagent with different amounts.

In order to predict the mechanism involved in the adsorption process, several kinetic models were used. Among them, the sorption kinetics was usually described by pseudo-first or pseudo-second order models. The kinetic behavior of stabilized SIRs was investigated as a function of amount of crosslinking reagent by batch adsorption equilibrium. Uncoated resins exhibited a faster kinetics than coated ones. It was possible to improve the kinetic performance of crosslinked resins with conditioning by using NaOH-NaCl mixture. The breakthrough profiles of SIRs were also influenced by amount of crosslinking reagent.

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