Vol 64 No 2 (2019): Journal of the Chilean Chemical Society
Original Research Papers
REACTION OF MOLECULAR OXYGEN WITH CHROMIUM, COBALT AND NICKEL METALLOCENES IN DIMETHYLSULFOXIDE. CORRELATION BETWEEN ITS POLAROGRAPHIC AND BOND LENGTHS PARAMETERS
Published
July 25, 2019
Keywords
- metallocenes,
- polarography,
- oxidation,
- reactivity
How to Cite
Zamudio, W., Duarte, N., García, A. M., & Campos Vallette, M. (2019). REACTION OF MOLECULAR OXYGEN WITH CHROMIUM, COBALT AND NICKEL METALLOCENES IN DIMETHYLSULFOXIDE. CORRELATION BETWEEN ITS POLAROGRAPHIC AND BOND LENGTHS PARAMETERS. Journal of the Chilean Chemical Society, 64(2). Retrieved from https://jcchems.com/index.php/JCCHEMS/article/view/1205
Copyright (c) 2019 Journal of the Chilean Chemical Society
This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.
Abstract
The reaction of oxidation with molecular oxygen in dimethyl sulfoxide is of order one in the metallocenes; the specific reaction constant decreases from nickel, chromium to cobalt. A reaction mechanism is proposed. The values of the polarographic constants and the bond lengths vary linearly with respect to the increase of the specific reaction constant but with opposite slopes.
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