Vol 64 No 2 (2019): Journal of the Chilean Chemical Society
Original Research Papers
CRYSTAL STRUCTURE AND HIRSHFELD SURFACE ANALYSIS OF (E)-5-PHENYL-3-((4- (TRIFLUOROMETHYL)BENZYLIDENE)AMINO)THIAZOLIDIN-2-IMINIUM BROMIDE
Published
July 25, 2019
How to Cite
Maharramov, A. M., Duruskari, G. S., Mammadova, G. Z., Khalilov, A. N., Aslanova, J. M., Cisterna, J., Cárdenas, A., & Brito, I. (2019). CRYSTAL STRUCTURE AND HIRSHFELD SURFACE ANALYSIS OF (E)-5-PHENYL-3-((4- (TRIFLUOROMETHYL)BENZYLIDENE)AMINO)THIAZOLIDIN-2-IMINIUM BROMIDE. Journal of the Chilean Chemical Society, 64(2). Retrieved from https://jcchems.com/index.php/JCCHEMS/article/view/1211
Copyright (c) 2019 Journal of the Chilean Chemical Society
This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.
Abstract
In the cation of the title salt, the central thiazolidine ring adopts an envelope conformation. In the crystal N-H ··· Br hydrogen bonds link the components into a bi-dimensional network with the cations and anions stacked parallel to plane (101). The molecular structure shows several positional disorders over -CF3 and thiazolidine fragments and these were modeled. The weak intermolecular interactions in the crystal structure are mainly constituted by H ··· F, H ··· π and H ··· Br. Hirshfeld surface analysis were used to verify the contributions of the different intermolecular interactions.
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